ABSTRACT:Graphene has attracted great attention and interest from global scientists. The fabrication methods and applications of three -dimensional graphene are under initial stage, thus, this review aims to describe the different synthetic processes for preparation three-dimensional graphene architectures and their merits and demerits; Moreover, the different fields of application such as adsorption, capacitive deionization, microbial fuel cells, supercapacitor and hydrogen storage are also reviewed; Finally, suggestions for further research are presented in the end of the paper.